I looked into the DUI unit prior to installing the HEI into my 225. From my experience, the whole purpose of the DUI company is to make the GM style HEI available to non GM motors. They use GM parts, or parts identicle to GM parts, and manufacture the distributor housing to be compatible to other applications. This isn't to say that DUI might not have made a few improvements to the design, but they are fundamentally the same and therefore I expect they work about the same. The main advantage I can see to going with the DUI is that they will curve the distributor to your application as part of the deal. While getting a HEI curved for a 231 dialed in for a 225 isn't difficult, it does require a little home work and some experimentation. If you have more money than time...go with the DUI, and report back on how well it works. If, like me, you have more time than money, do a search on HEI, print everything, read it until you understand, then go spend around $200 (new-reman) or less for used stuff and enjoy the upgrade.
If I had a motor that never came with a HEI, I would go DUI without hesitation.
Yet another uninformed opinion from me.